Chemical Engineering Thermodynamics

451. What is the degree of freedom for two miscible (non-reacting) substances in vapor-liquid equilibrium forming an azeotrope?

  1. 0
  2. 1
  3. 2
  4. 3

Correct answer: (C)
2

452. What is the number of degree of freedom for a system of two miscible non-reacting species in vapor-liquid equilibrium forming an azeotrope?

  1. 0
  2. 2
  3. 1
  4. 3

Correct answer: (C)
1

453. What is the number of degrees of freedom for liquid water in equilibrium with a mixture of nitrogen and water vapor?

  1. 2
  2. 0
  3. 3
  4. 1

Correct answer: (A)
2

454. What is the ratio of adiabatic compressibility to isothermal compressibility?

  1. 1
  2. < 1
  3. > 1
  4. >> 1

Correct answer: (B)
< 1

456. What is the value of ln y (where y = activity co-efficient) for ideal gases?

  1. Zero
  2. Unity
  3. Infinity
  4. Negative

Correct answer: (A)
Zero

457. What is the value of maximum COP in case of absorption refrigeration, if refrigeration provided is at temperature, TR (where, T1 and T2 are source & surrounding temperatures respectively.)?

  1. TR/(T2 - TR) × (T1 - T2)/T1
  2. TR/(T2 - TR) × T1/(T1 - T2)
  3. TR/(T1 - TR) × (T1 - T2)/T1
  4. None of these

Correct answer: (A)
TR/(T2 - TR) × (T1 - T2)/T1

458. When a gas in a vessel expands, its internal energy decreases. The process involved is

  1. Reversible
  2. Irreversible
  3. Isothermal
  4. Adiabatic

Correct answer: (A)
Reversible

459. When a gas is subjected to adiabatic expansion, it gets cooled due to

  1. Decrease in velocity
  2. Decrease in temperature
  3. Decrease in kinetic energy
  4. Energy spent in doing work

Correct answer: (D)
Energy spent in doing work

460. When a system in equilibrium is subjected to a change in temperature, pressure or concentration, the equilibrium is displaced in a direction which tends to undo the effect of the change. This is called the

  1. Le-Chatelier principle
  2. Kopp's rule
  3. Law of corresponding state
  4. Arrhenius hypothesis

Correct answer: (A)
Le-Chatelier principle

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